%0 Book
%T Synthesis of functionalized 2-(arylthio)benzoates by cyclization of 3-arylthio-1-silyloxy-1,3-butadienes with 3-silyloxy-2-en-1-ones, 3-alkoxy-2-en-1-ones, 1,1-diacylcyclopropanes, and dimethyl acetylenedicarboxylate
%A Iqbal, Inam
%D 2009
%G English
%F 605638799
%O vorgelegt von Inam Iqbal
%O Rostock, Univ., Mathematisch-Naturwiss. Fak., Diss., 2009
%X The work presented in this dissertation is concerned with the regioselective synthesis of functionalizeddiarylsulfides. The first chapter includes the synthesis of functionalized 2-(phenylthio)benzoates, containing a halogenated side chain, by domino ‘[3+3] cyclization / Homo-Michael' reactions of 1-trimethylsilyloxy-3-arylthio-1,3-butadienes with 1,1-diacylcyclopropanes. In the second chapter, a regioselective synthesis of 2-(arylthio)benzoates by the first [3+3] cyclizations of 3-arylthio-1-silyloxy-1,3-butadienes with 3-alkoxy-2-en-1-ones is reported. In the third chapter, the synthesis of 5-arylthio-3-hydroxyphthalates by the first [4+2] cycloadditions of 3-arylthio-1-silyloxy-1,3-butadienes with dimethyl acetylenedicarboxylate is reported.
%L 540
%9 theses
%9 Text
%9 Hochschulschrift
%U http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2009-0141-8
%U http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2009-0141-8&pdf
%U http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2009-0141-8