%0 Book
%T New aspects in homogeneous hydrogenation: development of practical rhodium phosphine catalysts and environmentally benign iron catalysts
%A Enthaler, Stephan
%D 2007
%G English
%F 562031685
%O vorgelegt von Stephan Enthaler
%O Rostock, Univ., Mathematisch-Naturwiss. Fak., Diss., 2008
%X This dissertation deals with the application of monodentate phosphine ligands in asymmetric hydrogenation of CC double bonds. The usefulness of rhodium catalysts containing phosphines based on the 4,5Dihydro3Hdinaphtho[2,1c;1,́2́e]phosphepine scaffold was demonstrated in the reduction of various prochiral substrates, since excellent enantioselectivities up to 96% ee were achieved. Furthermore, the properties of ironbased catalysts were studied in the field of transfer hydrogenation. Here high catalyst activities up to 2500 h-1 were obtained in the reduction of ketones.
%L 540
%9 theses
%9 Text
%9 Hochschulschrift
%U http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2008-0008-7
%U http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2008-0008-7&pdf
%U http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2008-0008-7