%0 Book %T Synthesis of heterocyclazines by Buchwald-Hartwig reaction and C-H activation %A Radolko, Jan %D 2025 %C Germany; Rostock %C Universität Rostock %G English %F 1986691993 %O vorgelegt von Jan Radolko %O Enthält Zeitschriftenartikel %O GutachterInnen: Peter Langer (Universität Rostock, Institut für Chemie) ; Thomas Müller (Heinrich-Heine-Universität Düsseldorf, Institut für Organische Chemie) %O Dissertation Universität Rostock 2026 Kumulative Dissertation %X This dissertation focuses on the development of methods for synthesizing new N- and O-doped aceanthrylene derivatives as well as N-doped azulenefluorene derivatives. The synthesis strategy employs Buchwald–Hartwig reactions and/or C–H activation for cyclization. In the process, C–C and C–N bonds are formed, yielding novel heterocycl[3.3.2]azines and heterocycl[4.2.2]azines. In addition, theoretical studies on aromaticity and energy levels, as well as experimental analyses of the electronic and optical properties, are conducted. %L 540 %9 theses %9 Text %9 Hochschulschrift %R 10.18453/rosdok_id00005827 %U https://purl.uni-rostock.de/rosdok/id00005827 %U https://doi.org/10.18453/rosdok_id00005827