%0 Book
%T Phosphaalkene ligands: a new perspective on Wittig-type transformations
%A Kushik
%D 2025
%C Germany; Rostock
%C Universität Rostock
%G English
%F 1979519145
%O vorgelegt von Kushik
%O Enthält Zeitschriftenartikel
%O GutachterInnen: Torsten Beweries (Leibniz-Institut für Katalyse e.V.) ; Christian Hering-Junghans (Leibniz-Institut für Katalyse e.V.) ; Gabriele Hierlmeier (Julius-Maximilians-Universität Würzburg)
%O Dissertation Universität Rostock 2025 Kumulative Dissertation
%X This thesis comprises four parts. First, attempts to synthesize phosphaalumenes using phospha‑Wittig reagents and Al(I) sources revealed transient intermediates that deactivate via dimerization or C–H activation. Second, a new azide‑Wittig reaction forms triazabutadienes from azides and aldehydes under mild conditions with broad scope. Third, bis‑phosphaalkene P,N,P ligands from carbazole give strong donors. Finally, Rh(I) complexes show distinct coordination and C–H activation, expanding phospha‑Wittig chemistry.<eng>
%L 540
%9 theses
%9 Text
%9 Hochschulschrift
%R 10.18453/rosdok_id00005664
%U https://purl.uni-rostock.de/rosdok/id00005664
%U https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00005664-5
%U https://d-nb.info/1412027020/34
%U https://doi.org/10.18453/rosdok_id00005664