%0 Book
%T The  chemistry of cyanophosphide and phosphafluorene: insights into structure and reactivity
%A Nasrullah, Ayu Afiqah
%D 2025
%C Germany; Rostock
%C Universität Rostock
%G English
%F 1976005590
%O vorgelegt von Ayu Afiqah Nasrullah
%O Enthält Zeitschriftenartikel
%O GutachterInnen: Christian Hering-Junghans (Leibniz-Institut für Katalyse e.V.) ; Eszter Baráth (Leibniz-Institut für Katalyse e.V.) ; Rudolf Pietschnig (Institut für Chemie, Universität Kassel)
%O Dissertation Universität Rostock 2025 Kumulative Dissertation
%X This thesis explores low-valent phosphorus chemistry using sterically demanding terphenyl (DippTer) substituents. It establishes the cyanophosphide [DippTerPCN]⁻ as a versatile platform, exhibiting the first P–CN/NC coordination isomerism upon O₂ oxidation and transfer reactivity to GeCl₂ (forming chlorogermylenes) and PCl₃/AsCl₃. A related DippTer-phosphafluorene enables Frustrated Lewis Pair (FLP) activation of terminal alkynes, yielding zwitterionic alkenyl phosphonium borates.<eng>
%L 540
%9 theses
%9 Text
%9 Hochschulschrift
%R 10.18453/rosdok_id00005658
%U https://purl.uni-rostock.de/rosdok/id00005658
%U https://doi.org/10.18453/rosdok_id00005658