%0 Book
%T Bio-inspired sustainable catalysis with base-metals and visible light
%A El-Sepelgy, Osama
%D 2025
%C Rostock
%C Universität Rostock
%G English
%F 1963633202
%O vorgelegt von Dr. Osama El-Sepelgy
%O Enthält Zeitschriftenartikel
%O GutachterInnen: Matthias Beller (Leibniz-Institut für Katalyse e.V.) ; Lutz Ackermann (Georg-August-Universität Göttingen) ; Armido Studer (Universität Münster)
%O Habilitationsschrift Universität Rostock 2025 Kumulative Habilitationsschrift
%X This thesis explores biomimetic catalytic systems inspired by metalloenzymes, utilizing ligand-to-metal charge transfer (LMCT) and metal-ligand cooperation (MLC) to enable efficient 3d-metal catalysis. By using earth-abundant metals, these approaches mimic enzymatic mechanisms where ligands actively participate in reactions. It covers cobalt catalysis for visible-light-induced radical desaturation and manganese pincer complexes for various redox transformations. The research integrates experimental and theoretical studies to optimize sustainable catalytic systems.<eng>
%L 540
%9 theses
%9 Text
%9 Hochschulschrift
%R 10.18453/rosdok_id00005152
%U https://purl.uni-rostock.de/rosdok/id00005152
%U https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00005152-3
%U https://d-nb.info/1393157084/34
%U https://doi.org/10.18453/rosdok_id00005152