%0 Book
%T Phosphorus-centered radicals and biradicals
%A Rosenboom, Jan
%D 2024
%C Rostock
%C Universität Rostock
%G English
%F 1951031288
%O vorgelegt von Jan Christoph Lukas Rosenboom
%O Enthält Zeitschriftenartikel
%O GutachterInnen: Axel Schulz (Universität Rostock) ; Jan Weigand (TU Dresden) ; Christian Müller (FU Berlin)
%O Dissertation Universität Rostock 2024 Kumulative Dissertation
%X This thesis deals with the synthesis, reactivity and spectroscopic properties of P-centered mono- and biradicals. First, the addition of aldehydes to the biradical [•P(μ-NTer)2P•], a classical concerted reaction mechanism, was investigated and elucidated in detail. In contrast, radical reactivity for this molecule was observed during the addition of bromoalkanes to [•P(μ-NTer)2P•]. This led to the synthesis of the persistent, phosphorus-centered monoradical [•P(μ-NTer)2PEt], which could also be detected by EPR spectroscopy as an intermediate during the radical reaction mechanism proposed here. Based on the reaction of [•P(μ-NTer)2P•] with bromoalkanes, the bridging of two biradical units was finally achieved with a dibromoalkane. From this, a phosphorus-centered disbiradical was synthesized and its special electronic situation was elucidated by means of extensive EPR experiments and quantum chemical calculations.<eng>
%L 540
%9 theses
%9 Text
%9 Hochschulschrift
%R 10.18453/rosdok_id00005096
%U https://purl.uni-rostock.de/rosdok/id00005096
%U https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00005096-8
%U https://d-nb.info/139044998X/34
%U https://doi.org/10.18453/rosdok_id00005096