%0 Book
%T Highly strained metallacycles: synthesis, electronic nature and reactivity of group 4 1-metallacyclobuta-2,3-dienes
%A Li, Sihan
%D 2024
%C Rostock
%C Universität Rostock
%G English
%F 1931412952
%O vorgelegt von Sihan Li
%O Enthält Zeitschriftenartikel
%O GutachterInnen: Torsten Beweries (Leibniz-Institut für Katalyse e.V.) ; Dominik Munz (Saarland University, Inorganic Chemistry: Coordination Chemistry)
%O Dissertation Universität Rostock 2024 Kumulative Dissertation
%X The first part mainly focuses on expanding the scope of this class of group 4 1-metallacyclobuta-2,3-dienes. Four new 1-metallacyclobuta-2,3-dienes were synthesized and fully characterized. Solid state NMR and EPR spectroscopy, as well as cyclic voltammetry were used for the first time on these complexes to gain a better understanding of the nature of these complexes. The second part of this thesis focuses on synthesis, characterization and reactivity towards carbodiimides. The third part explores the reactivity of 1-metallacyclobuta-2,3-dienes with diazenes.<eng>
%L 540
%9 theses
%9 Text
%9 Hochschulschrift
%R 10.18453/rosdok_id00004877
%U https://purl.uni-rostock.de/rosdok/id00004877
%U https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00004877-8
%U https://d-nb.info/137315067X/34
%U https://doi.org/10.18453/rosdok_id00004877