%0 Book %T Synthesis of polycyclic heteroaromatic hydrocarbons by C-H activation reactions: application of cycloisomerization and Pd-catalyzed cross-coupling reactions %A Khomutetckaia, Aleksandra %D 2024 %C Rostock %C Universität Rostock %G English %F 1930546645 %O vorgelegt von Aleksandra Khomutetckaia %O Enthält Zeitschriftenartikel %O Zeitschriftennachweis: 1. Aleksandra Khomutetckaia, Peter Ehlers, Alexander Villinger, Peter Langer. Synthesis and Properties of Azadibenzo[a,e]pyrenes. European Journal of Organic Chemistry. 2024, e202301299. DOI: 10.1002/ejoc.202301299. Online ISSN:1099-0690. Print ISSN:1434-193X. 2. Aleksandra Khomutetckaia, Niels Hildebrandt, Peter Ehlers, Alexander Villinger, Peter Langer. Synthesis and Properties of Diindeno[1,2,3-cd:1,2,3-mn]pyrene and Two of Its Aza-Analogs. European Journal of Organic Chemistry. 2023, e20230110. DOI: 10.1002/ejoc.202301101. Online ISSN:1099-0690. Print ISSN:1434-193X. 3. Aleksandra Khomutetckaia, Peter Ehlers, Alexander Villinger, Peter Langer. Synthesis and Properties of Benzo[h]imidazo[1,2-a]quinolines and 1,2a-Diazadibenzo[cd,f]azulenes. The Journal of Organic Chemistry. 2023, 88, 7929–7939. DOI: 10.1021/acs.joc.2c02738. Online ISSN 1520-6904. 4. Erich Ammon, Aleksandra Khomutetckaia, Alexander Villinger, Peter Ehlers, Peter Langer. Serendipitous discovery of Pd-catalyzed intramolecular cyclization of ortho-bromo(hetero)aryl-substituted (hetero)aryl-1,2-diketones: Applications in the synthesis of carba- and heterocyclic benzoin derivatives. Tetrahedron. 2023, 135, 133335. DOI: 10.1016/j.tet.2023.133335. ISSN 0040-4020 %O GutachterInnen: Peter Langer (Universität Rostock) ; Thomas J.J. Müller (Heinrich-Heine-Universität Düsseldorf) %O Dissertation Universität Rostock 2024 Kumulative Dissertation %X This dissertation focusses on the development of new synthetic routes to polycyclic aromatic hydrocarbons containing five-, six-, and seven-membered heterocyclic rings and the characterisation of these novel compounds. The synthetic investigations were directed to the application of C-H activation reaction. In particular, Pd-catalyzed C-H activations as well as acid mediated cycloisomerization reaction of 2-alkynyl biaryl derivatives were employed as key ring-closing synthesis steps. %L 540 %9 theses %9 Text %9 Hochschulschrift %R 10.18453/rosdok_id00004866 %U https://purl.uni-rostock.de/rosdok/id00004866 %U https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00004866-5 %U https://d-nb.info/1372071865/34 %U https://doi.org/10.18453/rosdok_id00004866