%0 Book %T Hydrogenation reactions catalyzed by manganese and molybdenum complexes: towards more sustainable redox reactions %A Both, Niklas Felix %D 2024 %C Rostock %C Universität Rostock %G English %F 1923956426 %O vorgelegt von Niklas Felix Both %O Enthält Zeitschriftenartikel %O GutachterInnen: Matthias Beller (Leibniz-Institut für Katalyse e.V.) ; Karl Kirchner (Technische Universität Wien) %O Dissertation Universität Rostock 2024 Kumulative Dissertation %X In this work, the synthesis of manganese complexes with easily accessible bidentate bis(NHC) ligands and their use as precatalysts for the hydrogenation of carboxylic acid esters as well as ketones, nitriles, N-heteroarenes and alkenes is described. Furthermore, the use of molybdenum catalysts with PNP pincer ligands for the semihydrogenation of alkynes is investigated. Finally, the bis(NHC) ligands are used to develop molybdenum-based catalyst systems for the hydrogenation of carboxylic acid esters. %L 540 %9 theses %9 Text %9 Hochschulschrift %R 10.18453/rosdok_id00004767 %U https://purl.uni-rostock.de/rosdok/id00004767 %U https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00004767-5 %U https://d-nb.info/1365412369/34 %U https://doi.org/10.18453/rosdok_id00004767