%0 Book %T Phosphonium salt catalysts for reductive and non-reductive CO2 fixation %A Ren, Changyue %D 2024 %C Rostock %C Universität Rostock %G English %F 1920802568 %O vorgelegt von Changyue Ren %O Enthält Zeitschriftenartikel %O GutachterInnen: Thomas Werner (Leibniz-Institut für Katalyse e.V.) ; Jan Paradies (Universität Paderborn, Department of Chemistry) %O Dissertation Universität Rostock 2024 Kumulative Dissertation %X In this thesis, a series of phosphonium salts were designed and used as catalysts for CO2 fixation and conversion to different valuable products via reductive and non-reductive reactions. Firstly, a phosphonium salt and two bifunctional phosphonium salts bearing perfluorinated side chains were prepared for the preparation of cyclic carbonate. Subsequently, phosphonium internal salt and a phosphonium methylcarbonate saltcatalyzed selectively reductive C-N bond formation reaction between amines and CO2 as C1-source with hydrosilanes as reducing agent were developed. %L 540 %9 theses %9 Text %9 Hochschulschrift %R 10.18453/rosdok_id00004759 %U https://purl.uni-rostock.de/rosdok/id00004759 %U https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00004759-0 %U https://d-nb.info/136195437X/34 %U https://doi.org/10.18453/rosdok_id00004759