%0 Book %T Thermal and photocatalytic C-C and C-N bond formation by atom-transfer radical additions and photocycloadditions %A Dasi, Rajesh %D 2023 %C Rostock %C Universität Rostock %G English %F 1918745048 %O vorgelegt von Rajesh Dasi %O Enthält Zeitschriftenartikel %O GutachterInnen: Malte Brasholz (Universität Rostock) ; Robert Francke (Leibniz-Institut für Katalyse) %O Dissertation Universität Rostock 2024 Kumulative Dissertation %X The content of this thesis is presented in three parts. In the first part, the radical functionalisation of biomass-derived 5-chloromethylfurfural (CMF) was described. In the second part, visible light-mediated triplet-sensitized [2+2] and [3+2] photocycloadditions of 2-cyanochromone with several alkenes were demonstrated using Iridium photocatalyst. The last part describes the a photocatalytic one-pot dehydrogenative Aza Paternò-Büchi reaction of dihydroquinoxalinones with substituted styrenes and acrylonitriles for the synthesis of diverse functionalised azetidine derivatives. %L 500 %9 theses %9 Text %9 Hochschulschrift %R 10.18453/rosdok_id00004745 %U https://purl.uni-rostock.de/rosdok/id00004745 %U https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00004745-8 %U https://d-nb.info/1358478007/34 %U https://doi.org/10.18453/rosdok_id00004745