%0 Book
%T Selective synthesis of 1,5-pentanediol from furfural derivatives over stable nickel-based catalysts
%A Al-Yusufi, Mohammed Abdullah Ahmed
%D 2022
%C Rostock
%C Universität Rostock
%G English
%F 1880511576
%O vorgelegt von Mohammed Abdullah Ahmed Al-Yusufi
%O GutachterInnen: Thomas Werner (Leibniz-Institut für Katalyse e.V. (LIKAT Rostock)) ; Tapio Salmi (Åbo Akademi University)
%O Dissertation Universität Rostock 2023
%X Reduced Ni on highly basic lanthanide supports in isopropanol (2-PrOH) was proved to be an efficient catalyst and an economically viable alternative to modified noble metal catalytic systems for the direct hydrogenolysis of tetrahydrofurfuryl alcohol (THFA) and furfural to 1,5-pentanediol (1,5-PeD). For the first time, a continuous catalytic transfer hydrogenolysis (CTH) process for the selective hydrogenolysis of THFA to 1,5-PeD was developed using Ni-La(R) in 2-PrOH. A maximum 1,5-PeD yield of 73% with an productivity of 1.4 mmol g(cat)-1 h-1 was achieved under continuous CTH conditions.<eng>
%L 540
%9 theses
%9 Text
%9 Hochschulschrift
%R 10.18453/rosdok_id00004535
%U https://purl.uni-rostock.de/rosdok/id00004535
%U https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00004535-9
%U https://d-nb.info/1320976492/34
%U https://doi.org/10.18453/rosdok_id00004535