%0 Book
%T Synthesis and Reactivity of Pacman Phosphanes
%A Eickhoff, Liesa Henrike
%D 2023
%C Rostock
%C Universität Rostock
%G English
%F 1857656997
%O vorgelegt von Liesa Henrike Eickhoff
%O Enthält Zeitschriftenartikel
%O GutachterInnen: Axel Schulz (Universität Rostock) ; Carsten von Hänisch (Philipps-Universität Marburg) ; Wolfgang Baumann (Leibniz-Institut für Katalyse e.V.)
%O Dissertation Universität Rostock 2023 Kumulative Dissertation
%X Pacman ligands can coordinate two metal centres and are inter alia used to achieve cooperative reaction behaviour. In this thesis, we transferred the concept to phosphorus chemistry. The substituents remaining on the phosphorus atoms in the resulting Pacman phosphanes strongly influence their properties, leading to the formation of different isomers or in the case of halogenated Pacman phosphanes to highly dynamic systems. During formation of dications by halide abstraction, redox isomerism is observed. Moreover, some of the Pacman phosphanes act as multidentate ligands.<eng>
%L 540
%9 theses
%9 Text
%9 Hochschulschrift
%R 10.18453/rosdok_id00004406
%U http://purl.uni-rostock.de/rosdok/id00004406
%U https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00004406-9
%U https://d-nb.info/1301016373/34
%U https://doi.org/10.18453/rosdok_id00004406