%0 Book %T Investigation of the light-induced copper-catalyzed allylic alkynylation: exploration of conditions, substrates and reaction mechanism %A Hünemörder, Paul Ewald Bernhard %D 2023 %C Rostock %C Universität Rostock %G English %F 1853930687 %O vorgelegt von Paul Ewald Bernhard Hünemörder %O GutachterInnen: Esteban Mejía (Leibniz-Institut für Katalyse) ; Shoubhik Das (University of Antwerp) %O Dissertation Universität Rostock 2023 %X This dissertation reports the investigation of the light-induced copper-catalyzed allylic alkynylation. Through further optimization, a reliable and robust protocol was established. In addition, the improved protocol was subjected to various substrates with varied success. Mechanistic studies were accompanied by spectroscopic inves-tigations with NMR, EPR and CV. Together with insights gathered from the perturbation of reaction conditions a new mechanistic proposal could be presented. %L 540 %9 theses %9 Text %9 Hochschulschrift %R 10.18453/rosdok_id00004395 %U http://purl.uni-rostock.de/rosdok/id00004395 %U https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00004395-5 %U https://d-nb.info/1298674956/34 %U https://doi.org/10.18453/rosdok_id00004395