%0 Book
%T Fundamentals determining activity and product selectivity in the oxidative coupling of methane over MnOx-M2WO4/SiO2 (M=Na, K, Rb, or Cs)
%A Zanina, Anna
%D 2023
%C Rostock
%C Universität Rostock
%G English
%F 1853798460
%O vorgelegt von Anna Zanina
%O Die Online-Ausgabe weicht von der Druckausgabe ab. Die Druckausgabe enthält den Volltext der Zeitschriftenartikel
%O Zeitschriftennachweis: 1. Zeynep Aydin, Anna Zanina, Vita A. Kondratenko, Jabor Rabeah, Jianshu Li, Juan Chen, Yuming Li, Guiyuan Jiang, Henrik Lund, Stephan Bartling, David Linke, Evgenii V. Kondratenko, Effects of N2O and Water on Activity and Selectivity in the Oxidative Coupling of Methane over MnNa2WO4/SiO2: Role of Oxygen Species, ACS Catalysis, ISSN 2155-5435, https://doi.org/10.1021/acscatal.1c04915, 12 pages. 2. Anna Zanina, Vita A. Kondratenko, Henrik Lund, Jianshu Li, Juan Chen, Yuming Li, Guiyuan Jiang, Evgenii V. Kondratenko, The Role of Adsorbed and Lattice Oxygen Species in Product Formation in the Oxidative Coupling of Methane over M2WO4/SiO2 (M=Na, K, Rb, Cs), ACS Catalysis, ISSN 2155-5435, https://doi.org/10.1021/acscatal.2c04916, 12 pages. 3. Anna Zanina, Vita A. Kondratenko, Henrik Lund, Jianshu Li, Juan Chen, Yuming Li, Guiyuan Jiang, Evgenii V. Kondratenko, Performance-defining factors of (MnOx)- M2WO4/SiO2 (M=Na, K, Rb, or Cs) catalysts in oxidative coupling of methane, Journal of Catalysis, ISSN 021-9517 (print) / 1090-2694 (web), https://doi.org/10.1016/j.jcat.2023.02.004, 12 pages
%O GutachterInnen: Evgenii Kondratenko (Leibniz-Institut für Katalyse e.V.) ; Reinhard Schomäcker (Institute of Chemistry, TU Berlin)
%O Dissertation Universität Rostock 2023 Kumulative Dissertation
%X The present thesis contributes to a better understanding of one of the most promising catalysts for the oxidative coupling of methane (OCM) reaction, i.e., MnOx-Na2WO4/SiO2. Oxygen species involved in selective and unselective pathways were investigated using O2 and N2O as the oxidants. Spatially resolved and steady-state kinetic analyses combined with oxygen isotopic exchange tests were used to identify the activity-defining descriptor over M2WO4/SiO2 (M=Na, K, Rb, or Cs). The effects of alkali metal for both bi- and trimetallic compositions on activity and selectivity were established<eng>
%L 540
%9 theses
%9 Text
%9 Hochschulschrift
%R 10.18453/rosdok_id00004386
%U http://purl.uni-rostock.de/rosdok/id00004386
%U https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00004386-5
%U https://d-nb.info/1297583310/34
%U https://doi.org/10.18453/rosdok_id00004386