%0 Book
%T Hydrogen bonding in mixtures of protic ionic liquids: influence on structure and thermodynamic properties
%A Golub, Benjamin
%D 2022
%C Rostock
%C Universität Rostock
%G English
%F 1845698223
%O vorgelegt von Benjamin Golub
%O Year of oral defence: 2023
%O Enthält Zeitschriftenartikel
%O GutachterInnen: Ralf Ludwig (Universität Rostock) ; Abenacer Idrissi (Université de Lille)
%O Dissertation Universität Rostock 2023 Kumulative Dissertation
%X In this work, the influence of hydrogen bonds on structure and thermodynamic properties of binary mixtures of protic ionic liquids (PILs), sharing the same cation, are investigated with molecular dynamics simulation. The observed non-ideal mixing behavior can be explained with the formation of complex hydrogen-bonded clusters. With the help of a newly developed simple lattice model the clusters can be described. Furthermore, the model shows that the mixing process is enthalpy-driven, not entropy-driven as one would expect.<eng>
%L 500
%9 theses
%9 Text
%9 Hochschulschrift
%R 10.18453/rosdok_id00004297
%U http://purl.uni-rostock.de/rosdok/id00004297
%U https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00004297-2
%U https://d-nb.info/1292078790/34
%U https://doi.org/10.18453/rosdok_id00004297