%0 Book
%T Hydrogen / deuterium exchange reactions: small variations for heavy changes
%A Bourriquen, Florian Marwan
%D 2022
%C Rostock
%C Universität Rostock
%G English
%F 1845697952
%O vorgelegt von Florian Bourriquen
%O Year of oral defence: 2023
%O Enthält Zeitschriftenartikel
%O GutachterInnen: Matthias Beller (Leibniz-Institut für Katalyse e.V.) ; Manuel van Gemmeren (Christian-Albrechts-Universität zu Kiel)
%O Dissertation Universität Rostock 2023 Kumulative Dissertation
%X This dissertation reports the development of new catalytic methodologies for deuterium incorporation into organic molecules. In a first part, the use of a simple Lewis acid is reported for the isotopic labelling of electron-rich (hetero)arenes. Next, two heterogeneous catalysts are presented for the labelling of comparable compounds: a first-generation iron-based system and a follow-up work using manganese. Both materials are easily prepared and fully characterised. Additionally, investigations were performed to gain insight on the mechanisms.<eng>
%L 540
%9 theses
%9 Text
%9 Hochschulschrift
%R 10.18453/rosdok_id00004295
%U http://purl.uni-rostock.de/rosdok/id00004295
%U https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00004295-8
%U https://d-nb.info/1292078758/34
%U https://doi.org/10.18453/rosdok_id00004295