%0 Book
%T Development of hydrogen isotope exchange methodologies for the deuteration of aromatic substrates
%A Kopf, Sara
%D 2022
%C Rostock
%C Universität Rostock
%G English
%F 1831239965
%O vorgelegt von Sara Kopf
%O Enthält Zeitschriftenartikel
%O GutachterInnen: Matthias Beller (Leibniz-Institut für Katalyse e.V., Rostock) ; Grégory Pieters (CEA Paris-Saclay) ; Matthias Tamm (TU Braunschweig)
%O Dissertation Universität Rostock 2022 Kumulative Dissertation
%X This thesis entails the development of practical and cost-efficient deuteration methodologies. The first C–H activation and deuteration of aromatic substrates using an earth-abundant manganese catalyst and transient directing groups was reported. Secondly, the transient directing group strategy was transferred to a ruthenium-catalyzed hydrogen isotope exchange reaction. Lastly, the electronic characteristics of pyridine derivatives were harnessed for a transition metal-free deuteration protocol. The results are expected to inspire future developments in sustainable hydrogen isotope exchange.<eng>
%L 540
%9 theses
%9 Text
%9 Hochschulschrift
%R 10.18453/rosdok_id00004135
%U http://purl.uni-rostock.de/rosdok/id00004135
%U https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00004135-3
%U https://d-nb.info/1293540013/34
%U https://doi.org/10.18453/rosdok_id00004135