%0 Book %T Structure-activity-selectivity relationships for iron-based catalysts in CO2 Fischer-Tropsch synthesis %A Skrypnik, Andrey %D 2022 %C Rostock %C Universität Rostock %G English %F 1831233967 %O vorgelegt von Andrey Skrypnik %O GutachterInnen: Evgenii Kondratenko (Leibniz-Institut für Katalyse e.V.) ; Malte Behrens (Christian-Albrechts-Universität zu Kiel) %O Dissertation Universität Rostock 2022 %X This study was aimed to evaluate the fundamentals for the purposeful preparation of Fe-based catalysts for CO2 conversion to higher hydrocarbons (C2+-hcs) with suppressed methane production. To this end tailored catalyst preparation and sophisticated material characterization by state-of-the-art techniques were combined with spatially resolved steady-state and transient kinetic analyses. To determine factors governing catalytic performance, the evolution of the microstructure and the phase composition of as-prepared iron oxides under CO2 Fischer-Tropsch synthesis conditions were established. %L 540 %9 theses %9 Text %9 Hochschulschrift %R 10.18453/rosdok_id00004133 %U http://purl.uni-rostock.de/rosdok/id00004133 %U https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00004133-0 %U https://d-nb.info/1293540005/34 %U https://doi.org/10.18453/rosdok_id00004133