%0 Book %T Influence of the pore structure on the catalytic performance of Rh-supported Zr-MOFs in the hydroformylation of olefins %A Sun, Yanjun %D 2020 %C Rostock %C Universität Rostock %G English %F 1798294605 %O vorgelegt von Yanjun Sun %O GutachterInnen: Axel Schulz (Institut für Chemie) ; Udo Kragl (Institut für Chemie) ; Hendrik Kosslick (Institut für Chemie) %O Dissertation Universität Rostock 2021 %X Zirconium-based metal-organic frameworks (Zr-MOFs) of different pore sizes and structure were synthesized and used for the preparation of the Rh-supported catalysts. The catalytic performance was studied in the hydroformylation of olefins to the corresponding aldehydes. A series of n-alk-1-enes of different chain length and bulky olefins with different size was used to study the influence of the pore size and structure. The results show that the Zr-MOF-based catalysts are very active and show high aldehyde selectivity. %L 540 %9 theses %9 Text %9 Hochschulschrift %R 10.18453/rosdok_id00003565 %U http://purl.uni-rostock.de/rosdok/id00003565 %U https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00003565-2 %U https://d-nb.info/1293537241/34 %U https://doi.org/10.18453/rosdok_id00003565