%0 Book
%T Development of 3d metal catalysts for redox reactions
%A Leonard, David
%D 2021
%C Rostock
%C Universität Rostock
%G English
%F 1789926815
%O vorgelegt von David Leonard
%O Enthält Zeitschriftenartikel
%O GutachterInnen: Matthias Beller (Leibniz Institute for Catalysis) ; Shoubhik Das (University of Antwerp)
%O Dissertation Universität Rostock 2021 Kumulative Dissertation
%X Herein is reported the application of non-noble metal-based catalytic systems for the homogeneous oxidation of organic substrates using air, specifically in amines and N-heterocycles. Simple 3d metal salts have been used, in combination with N-ligands, to facilitate the oxidative cleavage of C(sp3)–C(sp3) bonds. These reactions have been studied, using spectroscopic methods, to propose plausible mechanistic pathways. We believe such deconstructive strategies can enable late-stage functionalisation of pharmaceuticals and the synthesis of drug metabolites.<eng>
%L 500
%9 theses
%9 Text
%9 Hochschulschrift
%R 10.18453/rosdok_id00003492
%U http://purl.uni-rostock.de/rosdok/id00003492
%U https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00003492-4
%U https://d-nb.info/1293536709/34
%U https://doi.org/10.18453/rosdok_id00003492