%0 Book %T Studies towards radical and metalhydride mediated carbonylation reactions %A Meyer, Tim %D 2021 %C Rostock %C Universität Rostock %G English %F 1759760560 %O vorgelegt von Tim Meyer %O Enthält Zeitschriftenartikel %O GutachterInnen: Xiao-Feng Wu (Universität Rostock, Leibniz-Institut für Katalyse e. V.) ; Fabio Ragaini (Universita degli Studi di Milano, Dipartimento di Chimica) %O Dissertation Universität Rostock 2021 Kumulative Dissertation %X In this dissertation, we present a new method for the Mn-catalyzed ring-opening carbonylation of cyclobutanols. Next, we describe the C-C coupling reaction of alkenylboronic acids and arendiazonium tetrafluoroborate salts to afford stilbenes. We then report the first Pd-catalyzed oxidative carbonylation in which the oxidant could be completely replaced by visible light. Oxalamides were obtained from the corresponding amines. Finally, we describe a direct one-step synthesis of ethylene glycol from paraformaldehyde. %L 540 %9 theses %9 Text %9 Hochschulschrift %R 10.18453/rosdok_id00003038 %U http://purl.uni-rostock.de/rosdok/id00003038 %U https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00003038-0 %U https://d-nb.info/129366376X/34 %U https://doi.org/10.18453/rosdok_id00003038