%0 Book
%T Structure-reactivity relationships in Cu/TEMPO catalyzed aerobic alcohol oxidation: mechanistic assessment by (coupled) operando spectroscopic tools
%A Adomeit, Sven
%D 2019
%C Rostock
%C Universität Rostock
%G English
%F 1727955498
%O vorgelegt von Sven Adomeit
%O GutacherInnen: Angelika Brückner (Universität Rostock, Leibniz-Institut für Katalyse e.V.) ;  Felix Tuczek (Christian-Albrechts-Universität zu Kiel, Institut für Anorganische Chemie)
%O Dissertation Universität Rostock 2019
%X Aerobic alcohol oxidation is a route to convert alcohols into aldehydes using homogenous Cu catalysts with O2 as the terminal oxidant. It is well-known that the Cu catalyst forms a Cu(I/II) shuttle during the reaction. To investigate still open issues coupled operando EPR/UV-vis/ATR-IR was used in a first step. Through this combination it was possible to observe distinctive effects of the structure and molar ratios of ligands/additives upon the redox behavior of the Cu(I/II) shuttle. The triple coupling was further developed into a 4-in-1 set-up by implementing X-ray absorption spectroscopy.<eng>
%L 540
%9 theses
%9 Text
%9 Hochschulschrift
%R 10.18453/rosdok_id00002740
%U http://purl.uni-rostock.de/rosdok/id00002740
%U https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00002740-2
%U https://d-nb.info/1293660558/34
%U https://doi.org/10.18453/rosdok_id00002740