%0 Book
%T New insights into the structure performance relationships of Ce-based catalysts for synthesis of organic carbonates using CO2
%A Prymak, Iuliia
%D 2019
%C Rostock
%C Universität Rostock
%G English
%F 1689009152
%O vorgelegt von Iuliia Prymak
%O GutachterInnen: Evgenii Kondratenko (Universität Rostock, Leibniz-Institut für Katalyse e.V.) ; Angelika Brückner (Universität Rostock, Leibniz-Institut für Katalyse e.V.)
%O Dissertation Universität Rostock 2019
%X This work focuses on the chemical utilization of CO2 in organic synthesis by means of direct carboxylation of C1-C2 alcohols (methanol and ethanol, respectively) to organic carbonates, e.g. dimethyl carbonate (DMC) and/or diethyl carbonate (DEC), over pure and P-modified Ce-Zr-O catalysts. The catalysts containing 80 mol% Ce and 20 mol% Zr exhibited the most efficient performance, which could be attributed to a good balance between the basic and acidic sites on its surface. The DMC yield was successfully improved further from 0.24% to 1.6% by phosphate modification of Ce0.8Zr0.2O2.<eng>
%L 540
%9 theses
%9 Text
%9 Hochschulschrift
%R 10.18453/rosdok_id00002616
%U http://purl.uni-rostock.de/rosdok/id00002616
%U https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00002616-6
%U https://d-nb.info/1293658936/34
%U https://doi.org/10.18453/rosdok_id00002616