%0 Book
%T Bio-based building blocks from 5-hydroxymethylfurfural via 1-hydroxyhexane-2,5-dione as intermediate
%A Woźniak, Bartosz
%D 2018
%C Rostock
%C Universität Rostock
%G English
%F 1048999467
%O vorgelegt von Bartosz Wozniak
%O Die Dissertation enthält Zeitschriftenartikel
%O Dissertation Universität Rostock 2019
%X This dissertation reports on the synthesis and applications of the biomass-derived 1-hydroxyhexane-2,5-dione (HHD). A new catalytic process was developed for the hydrogenation/hydrolytic ring opening of 5-hydroxymethylfurfural (5-HMF) resulting in the formation of HHD in good yields. Furthermore, HHD was converted to useful follow-up products including pyrroles and cyclopentanone derivatives. Additionally, readily accessible rhenium(VII) oxide was used for the catalytic deoxydehydration of renewable triols under solvent-free and aerobic conditions resulting in formation of the hydroxy-alkenes.<eng>
%L 540
%9 theses
%9 Text
%9 Hochschulschrift
%R 10.18453/rosdok_id00002403
%U http://purl.uni-rostock.de/rosdok/id00002403
%U https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00002403-7
%U https://d-nb.info/1293655481/34
%U https://doi.org/10.18453/rosdok_id00002403