%0 Book
%T Selective oxidation of C16 macrocyclic diene to epoxides and ketones
%A Jaime Treviño, Diego Alberto
%D 2017
%C Rostock
%C Universität Rostock
%G English
%F 1042003475
%O vorgelegt von Lic. Diego A. Jaime Trevin̂o
%O Dissertation Universität Rostock 2017
%X In the present work, two approaches were followed in the oxidation of the macrocyclic diene 1,9-cyclohexadecadiene. Firstly, an epoxidation using hydrogen peroxide as oxidant was revised. A set of precursors used to form the peroxotungstophosphate active catalyst and a set of phase transfer catalyst were screened. The conversion and selectivity to the target epoxide varied pending on the precursor and PTC of choice. Secondly, a Wacker-type oxidation was done using different palladium complexes. Among them, a specific type of complexes showed a higher selectivity to the target ketone.<eng>
%L 540
%9 theses
%9 Text
%9 Hochschulschrift
%R 10.18453/rosdok_id00002353
%U http://purl.uni-rostock.de/rosdok/id00002353
%U https://doi.org/10.18453/rosdok_id00002353