%0 Book
%T Isomerization of allylic alcohols to the ketones catalyzed by first-row transition metal pincer complexes
%A Xia, Tian
%D 2018
%C Rostock
%C Universität Rostock
%G English
%F 1026618800
%O vorgelegt von Tian Xia
%O Dissertation Universität Rostock 2018
%X This thesis mainly describes the isomerization of allylic and homo-allylic alcohols to the corresponding carbonyl compounds in the presence of inexpensive transition metal complexes. [Fe(PNP)(CO)HCl] (PNP=di-(2-diisopropylphosphanyl-ethyl)amine), activated in situ with KOtBu, is a highly active catalyst for the isomerization of allylic and homo-allylic alcohols to ketones without an external hydrogen supply. High reaction rates were obtained at 80 oC, but the catalyst is also sufficiently active at room temperature with most substrates.<eng>
%L 540
%9 theses
%9 Text
%9 Hochschulschrift
%R 10.18453/rosdok_id00002267
%U http://purl.uni-rostock.de/rosdok/id00002267
%U https://nbn-resolving.org/urn:nbn:de:gbv:28-diss2018-0103-8
%U https://d-nb.info/1293652946/34
%U https://doi.org/10.18453/rosdok_id00002267