Hydrogen generation from the chemical energy carrier methanol: mechanistic insights into the ruthenium-catalysed dehydrogenation reaction and the implementation of a novel base-metal catalyst system Vogt, Lydia Katharina , 1989- (VerfasserIn) Beller, Matthias , 1962- (GutachterIn) Laurenczy, Gàbor , 1954- (GutachterIn) Universität Rostock (Grad verleihende Institution) Universität Rostock Mathematisch-Naturwissenschaftliche Fakultät (Grad verleihende Institution) Text theses Text Hochschulschrift 2017 2017 eng electronic resourceremoteComputermedienOnline-Ressource1 Online-Ressource This thesis deals with the aqueous-phase reforming of methanol catalysed by homogeneous pincer complexes. Based on extensive kinetic experiments, spectroscopic investigations and supporting theoretical calculations, a complete mechanistic cycle could be proposed for a Ru-pincer catalyst and its methylated derivative. Furthermore, a highly stable catalyst system based on the base metal manganese was implemented for the low-temperature dehydrogenation of methanol.<eng> submitted by M. Sc. Lydia Katharina Vogt (née Neumann) Dissertation Universität Rostock 2017 540 35.99 http://rosdok.uni-rostock.de/resolve/urn/urn:nbn:de:gbv:28-diss2017-0086-0 Hydrogen generation from the chemical energy carrier methanol--(DE-627)890763178 urn:nbn:de:gbv:28-diss2017-0086-0 oclc: 992939282 ppn: (DE-627)892902728