Synthesis and characterization of new CN-based transition metal complexes Al-Ramadhani, Omar Mowafaq Younis , 1976- (VerfasserIn) Schulz, Axel , 1967- (GutachterIn) Rosenthal, Uwe , 1950- (GutachterIn) Universität Rostock (Grad-verleihende Institution) Universität Rostock Mathematisch-Naturwissenschaftliche Fakultät (Grad-verleihende Institution) Text theses Text Hochschulschrift 2016 2016 eng electronic resourceremoteComputermedienOnline-Ressource1 Online-Ressource In the first part of this thesis the coordination behavior for P(CN)3 was studied, for preparing CN-rich phosphorous compounds from the reaction of P(CN)3 with weakly coordinating anions, Lewis bases, transition metal complexes and room temperature ionic liquids. In the second part of this thesis the new transition metal complexes from tetracyanopyrrole were synthesized. Remarkably, a new 1D-coordination polymer based on tetracyanopyrrolide could be isolated. Additionally, new TCP-salts of the type [R3NH]TCP (R= Me or nPr) were synthesized. All synthesized compounds were fully characterized.<eng> vorgelegt von Omar Mowafaq Younis Al-Ramadhani Dissertation Universität Rostock 2016 540 35.49 http://purl.uni-rostock.de/rosdok/id00001837 Synthesis and characterization of new CN-based transition metal complexes--(DE-627)876432755 urn:nbn:de:gbv:28-diss2017-0001-6 doi: 10.18453/rosdok_id00001837 oclc: 968698060 ppn: (DE-627)876717504