Catalysis with porous MOFs: structure-catalytic property-relationships in the hydroformylation of olefins over Rh supported metal-organic frameworks metal-organic frameworks Vu, Toan , 1976- Text theses Text Hochschulschrift 2014 2014 eng electronic resourceremoteComputermedienOnline-Ressourcetext/htmlapplication/pdfOnline-Ressource Ill., graph. Darst. It deals with preparation, characterization, and catalytic testing of Rh supported catalysts based on MOFs using hydroformylation as a model reaction. The influence of the MOF support on the catalytic performance (Structure-Catalytic Property-Relationships) is emphasized. Different MOF structures and pore sizes were synthesized, Rh immobilized, characterized, and tested. Results show that single site catalysts are achieved. The catalytic performance is affected by the structure, texture, and porosity of the MOF support. The linker orientation is of importance leading to single-file diffusion. by Toan Van Vu Rostock, Univ., Mathematisch-Naturwiss. Fak., Diss., 2014 546.634595 547.215 540 35.99 http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2015-0215-6 http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2015-0215-6&pdf http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2015-0215-6 Catalysis with porous MOFs--(DE-627)792796519 urn:nbn:de:gbv:28-diss2015-0215-6 oclc: 932420894 ppn: (DE-627)844207713