Tetracyanidoborates with triply charged rare earth metal cations and their optical properties Hackbarth, Liisa , 1984- Text theses Text Hochschulschrift 2015 2015 eng electronic resourceremoteComputermedienOnline-Ressourcetext/htmlapplication/pdfOnline-Ressource Illustrationen, Diagramme A new group of tetracyanidoborates - tetracyanidoborates with trivalent rare earth metal cations - was synthesized. The rare earth tetracyanidoborates form isostructural groups, e.g. [LRE(H2O)5][B(CN)4]3•0.5 H2O, with LRE3+ = La, Ce, Pr, Nd, Sm, Eu, Gd and [HRE(H2O)7][B(CN)4]3 with HRE3+ = Tb, Dy, Ho, Er, Tm, Yb, Lu and Y. These tetracyanidoborates exhibit rare earth cation specific luminescence properties which are improved by the tetracyanidoborate anion. Therefore, the tetracyanidoborates with trivalent rare earth metal cations could have possible applications in phosphors. vorgelegt von Liisa Hackbarth aus Rostock Rostock, Univ., Mathematisch-Naturwiss. Fak., Diss., 2015 546.671 540 35.40 http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2015-0198-7 http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2015-0198-7&pdf http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2015-0198-7 Tetracyanidoborates with triply charged rare earth metal cations and their optical properties--(DE-627)841260893 urn:nbn:de:gbv:28-diss2015-0198-7 ppn: (DE-627)842367063