Laser control and spectroscopy of molecular vibrations and reaction dynamics Lisaj, Mateusz , 1986- Text theses Text Hochschulschrift 2015 2015 eng electronic resourceremoteComputermedienOnline-Ressourcetext/htmlapplication/pdfOnline-Ressource Ill., graph. Darst. The main subjects of this work are the ultrafast laser driven quantum dynamics of collective CO vibrations in a metal-dicarbonyl complex. The fundamental insights into the interactions responsible for bond dissociation are obtained by using shaped laser pulses to steer molecular quantum dynamics. Specifically, CpCo(CO)2 is studied on the basis of a four-dimensional reactive potential energy surface (PES). It is shown that two perpendicularly polarized IR laser pulses can be used to trigger an alternating localization of the vibration within one CO bond. vorgelegt von Mateusz Lisaj Rostock, Univ., Mathematisch-Naturwiss. Fak., Diss., 2015 541.28 540 UH 5710 35.25 http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2015-0132-4 http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2015-0132-4&pdf http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2015-0132-4 Laser control and spectroscopy of molecular vibrations and reaction dynamics--(DE-627)832568392 urn:nbn:de:gbv:28-diss2015-0132-4 oclc: 935899818 ppn: (DE-627)833612840