Development of palladium nanoparticles based catalysts for aerobic oxidation of 5-hydroxymethylfurfural and glycerol Siyo, Baraa , 1985- Text theses Text Hochschulschrift 2014 2014 eng electronic resourceremoteComputermedienOnline-Ressourcetext/htmlapplication/pdfOnline-Ressource Ill., graph. Darst. Palladium nanoparticles were synthesized by the polyol method. The prepared NPs were deposited onto supports and applied in 5-hydroxymethylfurfural (HMF) and glycerol (GLY) oxidation. A high yield of 2,5-furandicarboxylic acid > 90 % connected with a relatively stable catalytic performance was obtained by HMF oxidation on a Pd/ZrO2/La2O3. A lactic acid yield of 75 % was obtained by GLY oxidation on a Pd-Ag/TiO2 which showed also a stable catalytic performance when the catalyst was recycled. The prepared catalysts were characterized by various methods before and after the oxidation reactions. vorgelegt von Baraa Siyo Rostock, Univ., Mathematisch-Naturwiss. Fak., Diss., 2014 660.29950284 660 Chemie 35.99 http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2014-0180-6 http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2014-0180-6&pdf http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2014-0180-6 Development of palladium nanoparticles based catalysts for aerobic oxidation of 5-hydroxymethylfurfural and glycerol--(DE-627)799257974 urn:nbn:de:gbv:28-diss2014-0180-6 oclc: 935767281 ppn: (DE-627)806814586