Synthesis of highly functionalized carbacycles, heterocycles and silylium-arene adducts by cyclocondensations, palladium catalyzed cross-coupling reactions and activation by [Me3Si]+ cation Ibad, Muhammad Farooq , 1982- Text theses Text Hochschulschrift 2012 2012 eng electronic resourceremoteComputermedienOnline-Ressourcetext/htmlapplication/pdfOnline-Ressource graph. Darst. The Me3SiOTf-mediated condensation of 1-ethoxy-2-fluoro-1,3-bis trimethylsilyloxy) 1,3-dienes with 3-cyanochromones afforded fluorinated azaxanthones or biaryls. The [4+2] cycloaddition of 1-ethoxy-2-fluoro-1,3-bis(trimethylsilyloxy)-1,3-diene with DMAD afforded dimethyl 4-fluoro-3,5-dihydroxyphthalate. Various arylated phthalates, naphthoates, indoles, are synthesized Pd(0)-catalyzed Suzuki cross-coupling reaction and studied. The experimental and theoretical study of the silylium arene adducts ([Me3Si-Ar][B(C6F5)4]) and the catalytic trimerisation of bissilylated diazomethane are studied. vorgelegt von Muhammad Farooq Ibad Rostock, Univ., Mathematisch-Naturwiss. Fak., Diss., 2012 35.49 http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2013-0037-7 http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2013-0037-7&pdf http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2013-0037-7 Synthesis of highly functionalized carbacycles, heterocycles and silylium-arene adducts by cyclocondensations, palladium catalyzed cross-coupling reactions and activation by [Me3Si]+ cation--(DE-627)737908734 urn:nbn:de:gbv:28-diss2013-0037-7 oclc: 934994899 ppn: (DE-627)739679139