Synthesis of 1-alkenylpyrenes and of fluorinated arenes by palladium(0)-catalyzed cross-coupling reactions and photophysical properties of the products Sharif Akbar, Muhammad , 1980- Text theses Text Hochschulschrift 2011 2011 eng electronic resourceremoteComputermedienOnline-Ressourcetext/htmlapplication/pdfOnline-Ressource graph. Darst. The palladium(0)-catalyzed Heck cross coupling reactions of 1-bromopyrene provided functionalized alkenylpyrenes with styrenes and acrylates by single fold Heck reactions. Suzuki-Miyaura cross coupling reactions of the differently substituted di and mono fluoro benzenes with different arylboronic acids afforded fluoro-substituted terphenyls with excellent site-selectivity. Sonogashira and Suzuki-Miyaura coupling reactions of 1,2-difluoro, 1,3-difluoro, 1,4-difluoro, 1-fluoro, tetraiodobenzenes and pentaiodobenzenes respectively provided tetra- and penta-alkynylated and arylbenzene products. vorgelegt von Muhammad Sharif Akbar Rostock, Univ., Mathematisch-Naturwiss. Fak., Diss., 2011 540 35.69 http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2011-0126-1 http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2011-0126-1&pdf http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2011-0126-1 Synthesis of 1-alkenylpyrenes and of fluorinated arenes by palladium(0)-catalyzed cross-coupling reactions and photophysical properties of the products--(DE-627)665573405 urn:nbn:de:gbv:28-diss2011-0126-1 oclc: 837879972 ppn: (DE-627)666752982