A calorimetric study of non-equilibrium structures on fast cooling (100 000 K/s) Adamovski, Serguei , 1972- Text theses Text Hochschulschrift 2010 2010 eng electronic resourceremoteComputermedienOnline-Ressourcetext/htmlapplication/pdfapplication/pdfOnline-Ressource Ill., graph. Darst. Present work describes an ultra-fast scanning calorimeter that is capable of controlled cooling and heating at rates up to 100 000 K/s as well as isothermal measurements with time resolution of 0.1 ms. The technique was applied to study crystallization kinetics of polymers and monodisperse n-alkanes. It is shown that the bend in the isothermal crystallization kinetics curve of n-alkanes is not the transition between formations of structures with different folding indexes, but it is rather caused by the interplay of different processes with different kinetics as well as a self-poisoning effect. submitted by Serguei Adamovski Rostock, Univ., Mathematisch-Naturwiss. Fak., Diss., 2010 Langzeitarchivierung gewährleistet pdager 536.63 530 33.61 http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2010-0196-0 http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2010-0196-0&pdf http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2010-0196-0 http://d-nb.info/1011895897/34 http://rosdok.uni-rostock.de/metadata/rosdok_disshab_000000000563 A calorimetric study of non-equilibrium structures on fast cooling (100 000 K/s)--(DE-627)641977573 urn:nbn:de:gbv:28-diss2010-0196-0 oclc: 729353910 ppn: (DE-627)642884315