Hydrogen generation from renewable resources Loges, Björn , 1980- Text theses Text Hochschulschrift 2009 2009 eng ger electronic resourceremoteComputermedienOnline-Ressourcetext/htmlapplication/pdfpdfOnline-Ressource Ill., graph. Darst. Hydrogen generation from 2-propanol and formic acid and its direct use in fuel cells was studied. 2-propanol was dehydrogenated with ruthenium diamine catalysts. Formic acid was decomposed selectively to hydrogen and carbon dioxide in a system containing ruthenium catalysts and formic acid amine adducts. The best catalyst activity and productivity were achieved with in situ generated ruthenium phosphine catalysts, e.g. [RuCl2(benzene)]2 / dppe (TOF = 900 h-1, TON = 260.000). The influence of irradiation with visible light has been described for the ruthenium phosphine catalysts. vorgelegt von Björn Loges Rostock, Univ., Mathematisch-Naturwiss. Fak., Diss., 2009 540 540 35.50 http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2010-0017-1 http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2010-0017-1&pdf http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2010-0017-1 http://rosdok.uni-rostock.de/metadata/rosdok_disshab_000000000384 http://d-nb.info/1001051432/34 http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2010-0017-1 Hydrogen generation from renewable resources--(DE-627)616810555 urn:nbn:de:gbv:28-diss2010-0017-1 oclc: 643191113 ppn: (DE-627)616990170