Highly strained metallacycles: synthesis, electronic nature and reactivity of group 4 1-metallacyclobuta-2,3-dienes Li, Sihan , 1995- (VerfasserIn) Beweries, Torsten , 1982- (AkademischeR BetreuerIn) Munz, Dominik , 1982- (AkademischeR BetreuerIn) Universität Rostock (Grad-verleihende Institution) Universität Rostock Mathematisch-Naturwissenschaftliche Fakultät (Grad-verleihende Institution) Text theses Text Hochschulschrift 2024 2024 eng ger electronic resourceremoteComputermedienOnline-Ressourceapplication/pdf1 Online-Ressource (VII, 111 Seiten) Illustrationen, Diagramme The first part mainly focuses on expanding the scope of this class of group 4 1-metallacyclobuta-2,3-dienes. Four new 1-metallacyclobuta-2,3-dienes were synthesized and fully characterized. Solid state NMR and EPR spectroscopy, as well as cyclic voltammetry were used for the first time on these complexes to gain a better understanding of the nature of these complexes. The second part of this thesis focuses on synthesis, characterization and reactivity towards carbodiimides. The third part explores the reactivity of 1-metallacyclobuta-2,3-dienes with diazenes.<eng> Open Access Urheberrechtsschutz 1.0 vorgelegt von Sihan Li Enthält Zeitschriftenartikel GutachterInnen: Torsten Beweries (Leibniz-Institut für Katalyse e.V.) ; Dominik Munz (Saarland University, Inorganic Chemistry: Coordination Chemistry) Dissertation Universität Rostock 2024 Kumulative Dissertation 540 547 540 https://purl.uni-rostock.de/rosdok/id00004877 https://doi.org/10.18453/rosdok_id00004877 https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00004877-8 https://d-nb.info/137315067X/34 Highly strained metallacycles: synthesis, electronic nature and reactivity of group 4 1-metallacyclobuta-2,3-dienes--(DE-627)1931413401 urn:nbn:de:gbv:28-rosdok_id00004877-8 doi: 10.18453/rosdok_id00004877 oclc: 1528469178 ppn: (DE-627)1931412952