Thermal and photocatalytic C-C and C-N bond formation by atom-transfer radical additions and photocycloadditions Dasi, Rajesh , 1996- (VerfasserIn) Brasholz, Malte , 1978- (AkademischeR BetreuerIn) Francke, Robert , 1982- (AkademischeR BetreuerIn) Universität Rostock (Grad-verleihende Institution) Universität Rostock Mathematisch-Naturwissenschaftliche Fakultät (Grad-verleihende Institution) Text theses Text Hochschulschrift 2023 2023 eng ger electronic resourceremoteComputermedienOnline-Ressourceapplication/pdf1 Online-Ressource (110 Seiten) Illustrationen, Diagramme The content of this thesis is presented in three parts. In the first part, the radical functionalisation of biomass-derived 5-chloromethylfurfural (CMF) was described. In the second part, visible light-mediated triplet-sensitized [2+2] and [3+2] photocycloadditions of 2-cyanochromone with several alkenes were demonstrated using Iridium photocatalyst. The last part describes the a photocatalytic one-pot dehydrogenative Aza Paternò-Büchi reaction of dihydroquinoxalinones with substituted styrenes and acrylonitriles for the synthesis of diverse functionalised azetidine derivatives.<eng> Open Access Urheberrechtsschutz 1.0 vorgelegt von Rajesh Dasi Enthält Zeitschriftenartikel GutachterInnen: Malte Brasholz (Universität Rostock) ; Robert Francke (Leibniz-Institut für Katalyse) Dissertation Universität Rostock 2024 Kumulative Dissertation 500 540 541 540 https://purl.uni-rostock.de/rosdok/id00004745 https://doi.org/10.18453/rosdok_id00004745 https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00004745-8 https://d-nb.info/1358478007/34 Thermal and photocatalytic C-C and C-N bond formation by atom-transfer radical additions and photocycloadditions--(DE-627)1918746788 urn:nbn:de:gbv:28-rosdok_id00004745-8 doi: 10.18453/rosdok_id00004745 oclc: 1503461251 ppn: (DE-627)1918745048