On the role of nitride and oxide supports for the charge state of isolated palladium catalysts Huang, Junhao , 1994- (VerfasserIn) Strunk, Jennifer , 1980- (AkademischeR BetreuerIn) Auer, Alexander A. , 1973- (AkademischeR BetreuerIn) Logsdail, Andrew (AkademischeR BetreuerIn) Universität Rostock (Grad-verleihende Institution) Universität Rostock Mathematisch-Naturwissenschaftliche Fakultät (Grad-verleihende Institution) Text theses Text Hochschulschrift 2023 17. April 2023 eng ger electronic resourceremoteComputermedienOnline-Ressourceapplication/pdf1 Online-Ressource (XVIII, 157 Seiten) Illustrationen, Diagramme In this dissertation, a series of isolated palladium catalysts were constructed, and the effect of support type, including oxide and nitride supports, on the charge state of the palladium center was investigated. Based on the periodic trend in electronegativity, a correlation was established between the formal oxidation state, computed Bader charge, and CO vibrational frequency, allowing the identification of appropriate models to better understand the coordination and electronic structure of palladium sites.<eng> Open Access Urheberrechtsschutz 1.0 vorgelegt von Junhao Huang GutachterInnen: Jennifer Strunk (Leibniz-Institut für Katalyse e.V.) ; Alexander Auer (Max-Planck-Institut für Kohlenforschung) ; Andrew Logsdail (Cardiff University) Dissertation Universität Rostock 2023 540 541 540 https://purl.uni-rostock.de/rosdok/id00004707 https://doi.org/10.18453/rosdok_id00004707 https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00004707-5 https://d-nb.info/1352014319/34 On the role of nitride and oxide supports for the charge state of isolated palladium catalysts--(DE-627)1911549227 urn:nbn:de:gbv:28-rosdok_id00004707-5 doi: 10.18453/rosdok_id00004707 oclc: 1477779191 ppn: (DE-627)1911516337