Development of 3d metal catalysts for redox reactions Leonard, David , 1995- (VerfasserIn) Beller, Matthias , 1962- (AkademischeR BetreuerIn) Das, Shoubhik , 1980- (AkademischeR BetreuerIn) Universität Rostock (Grad-verleihende Institution) Universität Rostock Mathematisch-Naturwissenschaftliche Fakultät (Grad-verleihende Institution) Text theses Text Hochschulschrift 2021 2021 eng electronic resourceremoteComputermedienOnline-Ressource1 Online-Ressource Herein is reported the application of non-noble metal-based catalytic systems for the homogeneous oxidation of organic substrates using air, specifically in amines and N-heterocycles. Simple 3d metal salts have been used, in combination with N-ligands, to facilitate the oxidative cleavage of C(sp3)–C(sp3) bonds. These reactions have been studied, using spectroscopic methods, to propose plausible mechanistic pathways. We believe such deconstructive strategies can enable late-stage functionalisation of pharmaceuticals and the synthesis of drug metabolites.<eng> vorgelegt von David Leonard Enthält Zeitschriftenartikel GutachterInnen: Matthias Beller (Leibniz Institute for Catalysis) ; Shoubhik Das (University of Antwerp) Dissertation Universität Rostock 2021 Kumulative Dissertation 500 540 540 35.17 http://purl.uni-rostock.de/rosdok/id00003492 https://doi.org/10.18453/rosdok_id00003492 https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00003492-4 https://d-nb.info/1293536709/34 Development of 3d metal catalysts for redox reactions--(DE-627)179337483X urn:nbn:de:gbv:28-rosdok_id00003492-4 doi: 10.18453/rosdok_id00003492 oclc: 1297823784 ppn: (DE-627)1789926815