Copper catalyzed sun fuel generation by CO2 and H2O reduction Kreft, Stefanie , 1985- (VerfasserIn) Beller, Matthias , 1962- (AkademischeR BetreuerIn) Ludwig, Ralf , 1961- (AkademischeR BetreuerIn) Universität Rostock (Grad-verleihende Institution) Universität Rostock Mathematisch-Naturwissenschaftliche Fakultät (Grad-verleihende Institution) Text theses Text Hochschulschrift 2019 2019 eng electronic resourceremoteComputermedienOnline-Ressource1 Online-Ressource Heterogeneous copper-based catalysts have been investigated for the photocatalytic H2O and CO2 reduction. Ex situ and in situ synthesized catalysts supported on inert silica have been developed for the photocatalytic proton reduction. The best supported photocatalyst achieved a significantly higher activity compared to the initial homogeneous precursor. In a second project highly porous photocatalysts have been synthesized, applied in aqueous CO2 reduction and characterized by in situ XAS, EPR and UV-vis measurements. An improved catalytic performance was observed by the addition of oxygen.<eng> vorgelegt von Stefanie Kreft GutachterInnen: Matthias Beller (Universität Rostock, Leibniz-Institut für Katalyse e.V.) ; Ralf Ludwig (Universität Rostock, Institut für Chemie) Enthält Zeitschriftenartikel Dissertation Universität Rostock 2019 540 541 540 35.17 http://purl.uni-rostock.de/rosdok/id00002594 https://doi.org/10.18453/rosdok_id00002594 https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00002594-8 https://d-nb.info/1293658618/34 Copper catalyzed sun fuel generation by CO2 and H2O reduction--(DE-627)1687288828 urn:nbn:de:gbv:28-rosdok_id00002594-8 doi: 10.18453/rosdok_id00002594 oclc: 1137262679 ppn: (DE-627)1687013330