Bio-based building blocks from 5-hydroxymethylfurfural via 1-hydroxyhexane-2,5-dione as intermediate Woźniak, Bartosz , 1991- (VerfasserIn) Vries, Johannes de (AkademischeR BetreuerIn) Barta, Katalin , 1980- (AkademischeR BetreuerIn) Universität Rostock (Grad-verleihende Institution) Universität Rostock Mathematisch-Naturwissenschaftliche Fakultät (Grad-verleihende Institution) Text theses Text Hochschulschrift 2018 2018 eng electronic resourceremoteComputermedienOnline-Ressource1 Online-Ressource This dissertation reports on the synthesis and applications of the biomass-derived 1-hydroxyhexane-2,5-dione (HHD). A new catalytic process was developed for the hydrogenation/hydrolytic ring opening of 5-hydroxymethylfurfural (5-HMF) resulting in the formation of HHD in good yields. Furthermore, HHD was converted to useful follow-up products including pyrroles and cyclopentanone derivatives. Additionally, readily accessible rhenium(VII) oxide was used for the catalytic deoxydehydration of renewable triols under solvent-free and aerobic conditions resulting in formation of the hydroxy-alkenes.<eng> vorgelegt von Bartosz Wozniak Die Dissertation enthält Zeitschriftenartikel Dissertation Universität Rostock 2019 540 661.8 660 35.17 http://purl.uni-rostock.de/rosdok/id00002403 https://doi.org/10.18453/rosdok_id00002403 https://nbn-resolving.org/urn:nbn:de:gbv:28-rosdok_id00002403-7 https://d-nb.info/1293655481/34 Bio-based building blocks from 5-hydroxymethylfurfural via 1-hydroxyhexane-2,5-dione as intermediate--(DE-627)1049056302 urn:nbn:de:gbv:28-rosdok_id00002403-7 doi: 10.18453/rosdok_id00002403 ppn: (DE-627)1048999467