Selective oxidation of C16 macrocyclic diene to epoxides and ketones Jaime Treviño, Diego Alberto , 1989- (VerfasserIn) Martin, Andreas , 1955- (AkademischeR BetreuerIn) Prüße, Ulf , 1966- (AkademischeR BetreuerIn) Universität Rostock (Grad-verleihende Institution) Universität Rostock Mathematisch-Naturwissenschaftliche Fakultät (Grad-verleihende Institution) Text theses Text Hochschulschrift 2017 2017 eng electronic resourceremoteComputermedienOnline-Ressource1 Online-Ressource In the present work, two approaches were followed in the oxidation of the macrocyclic diene 1,9-cyclohexadecadiene. Firstly, an epoxidation using hydrogen peroxide as oxidant was revised. A set of precursors used to form the peroxotungstophosphate active catalyst and a set of phase transfer catalyst were screened. The conversion and selectivity to the target epoxide varied pending on the precursor and PTC of choice. Secondly, a Wacker-type oxidation was done using different palladium complexes. Among them, a specific type of complexes showed a higher selectivity to the target ketone.<eng> vorgelegt von Lic. Diego A. Jaime Trevin̂o Dissertation Universität Rostock 2017 540 35.17 http://purl.uni-rostock.de/rosdok/id00002353 Selective oxidation of C16 macrocyclic diene to epoxides and ketones--(DE-627)100876406X urn:nbn:de:gbv:28-diss2018-0180-6 doi: 10.18453/rosdok_id00002353 ppn: (DE-627)1042003475