Palladium-catalyzed synthesis of pyrrole-, indole- and phenanthridine-fused polycyclic aromatic compounds from ortho-dihaloarenes Phạm, Ngô NghĨa , 1984- (VerfasserIn) Langer, Peter , 1969- (GutachterIn) Schmidt, Andreas , 1964- (GutachterIn) Universität Rostock (Grad verleihende Institution) Universität Rostock Mathematisch-Naturwissenschaftliche Fakultät (Grad verleihende Institution) Text theses Text Hochschulschrift 2016 2016 eng electronic resourceremoteComputermedienOnline-Ressource1 Online-Ressource Convenient palladium-catalyzed syntheses of polycyclic nitrogen heterocycles from ortho-dihaloarenes were developed. First, syntheses of pyrrole-fused derivatives via domino C-C/C-N coupling of ortho-dihaloarenes with imines were accomplished. Employment of ortho-dihaloarenes for sequential regioselective Suzuki reaction/double C-N coupling afforded corresponding indole-fused structures. Finally, syntheses of previously unexplored phenanthridine-fused architectures by regioselective Sonogashira reaction followed by domino or one-pot C-N coupling/hydroamination/C-H arylation were described.<eng> vorgelegt von Ngo Nghia Pham aus Vietnam Dissertation Universität Rostock 2017 547.64 547.615 547.2 540 35.99 http://rosdok.uni-rostock.de/resolve/urn/urn:nbn:de:gbv:28-diss2018-0041-4 https://doi.org/10.18453/rosdok_id00002047 https://nbn-resolving.org/urn:nbn:de:gbv:28-diss2018-0041-4 https://d-nb.info/1293651931/34 Palladium-catalyzed synthesis of pyrrole-, indole- and phenanthridine-fused polycyclic aromatic compounds from ortho-dihaloarenes--(DE-627)881333263 urn:nbn:de:gbv:28-diss2018-0041-4 doi: 10.18453/rosdok_id00002047 oclc: 1030989822 ppn: (DE-627)1018341501