@Book{817979794,
author="Domke, Lutz",
title="Asymmetric hydrogenation and hydroformylation of 1,1-disubstituted olefins",
year="2014",
abstract="Asymmetric hydrogenation as well as hydroformylation of 1,1-disubstituted olefins were investigated. Thus, an O-silylprotected dehydro lactate, a N,O-ketene acetal and a range of dehydro beta2-homoalanine derivatives were hydrogenated enantioselectively yielding chiral products with high stereoselectivities. Furthermore, the rhodium-catalyzed asymmetric hydroformylation of an alpha-phosphorylated styrene derivative was examined and the scope could be expanded using new phosphite-phosphoramidite ligands. In addition, HP-NMR experiments gave some indication of the active catalyst-complex.",
note="vorgelegt von Lutz Domke",
note="Rostock, Univ., Mathematisch-Naturwiss. Fak., Diss., 2014",
url="http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2015-0026-6",
url="http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2015-0026-6&pdf",
url="http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2015-0026-6",
language="English"
}