@Book{779460162, author="Thiel, Indre", title="Synthesis of novel cyclopentadienyl cobalt(I)-complexes and their application in [2+2+2] cycloaddition reactions", year="2013", abstract="This thesis describes the synthesis of cyclopentadienyl (Cp) cobalt(I)-complexes of the type [CpCo(I)L1L2]. Systematic variation of the neutral ligands (L) demonstrated that the use of two different ligands -- namely an olefin and a phosphite ligand -- proved to be superior to the homoleptic equivalents, providing sufficient activity in catalytic [2+2+2] cycloaddition reactions as well as appropriate stability. Further modifications resulted in air-stable and recyclable catalysts, which could be supported on a solid-phase, representing the first active, supported, CpCo(I)-based catalyst.", note="Indre Thiel", note="Rostock, Univ., Mathematisch-Naturwiss. Fak., Diss., 2013", url="http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2014-0044-1", url="http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2014-0044-1&pdf", url="http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2014-0044-1", language="English" }