@Book{718223721, author="Ali, Iftikhar", title="Synthesis of substituted 1-deazapurines via Pd/Cu catalysed C-H activation, substituted naphthyridines, quinoxalines, and trifluoromethyl-substituted arenes by Pd(0)-catalysed cross-coupling reactions", year="2011", abstract="The Pd/Cu catalyzed reactions of 3H-imidazo[4,5-b]pyridines (1-deazapurines) via C-H bond activation provided arylated 1-deazapurines. The arylation took place at position 2 of the 1-deazapurines. Pd(0)-catalysed Suzuki-Miyaura cross coupling reactions of 5,7-dichloro-1,6-naphthyridine, 2,6-dichloroquinoxaline and 2,4-dichloro-1-(trifluoromethyl)benzene with different arylboronic acids afforded aryl-substituted naphthyridines, quinoxalines and trifluoromethyl-substituted di- and terphenyls with excellent site-selectivity. The first attack occurred at the more electronically deficient and sterically less hindered position.", note="vorgelegt von Iftikhar Ali", note="Rostock, Univ., Mathematisch-Naturwiss. Fak., Diss., 2012", url="http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2012-0039-6", url="http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2012-0039-6&pdf", url="http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2012-0039-6", language="English" }