@Book{66775279X,
author="Zhou, Shaolin",
title="Development of new homogeneous (enantioselective) hydrogenation catalysts based on bio-relevant metals",
year="2011",
abstract="This thesis presents the study and development of new catalysts based on first row transition metals for the (asymmetric) reduction of different C=O and C=N bonds. An iron cluster catalyst with a chiral tetradentate P2N2 ligand was discovered to catalyze the asymmetric transfer hydrogenation of N-diphenylphosphinylketimines. Subsequently the combination of a chiral Br{\o}nsted acid with a well-defined Shvo type iron complex creates an active catalyst which could hydrogenate a variety of N-aryl ketimines to amines using molecular hydrogen. Finally, an iron cluster catalyst was discovered to catalyze the reduction of amides with inexpensive PMHS.",
note="vorgelegt von Shaolin Zhou",
note="Die elektronische Ausgabe weicht von der gedruckten ab. Die gedruckte enth{\"a}lt Beitr{\"a}ge aus verschiedenen Zeitschriften",
note="Rostock, Univ., Mathematisch-Naturwiss. Fak., Diss., 2011",
url="http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2011-0127-7",
url="http://rosdok.uni-rostock.de/resolve?urn=urn:nbn:de:gbv:28-diss2011-0127-7&pdf",
url="http://nbn-resolving.de/urn:nbn:de:gbv:28-diss2011-0127-7",
language="English"
}